Videolan released VLC 2.0.2 today.
If you update VLC, then VLC Remote will crash.
Update, the VLC Remote update has been approved, so please update to 6.0.2 and all should be well.
I have submitted a fix to Apple, but as ever, it’ll take about a week for them to approve it. In the meantime, the best bet is to downgrade to VLC 2.0.1 which you can get here: